case studies

Chlor-Alkali Waste to Pure H2

Chongqing Wintinwe Chlor-Alkali was venting a hydrogen-rich waste stream while its own campus consumed hydrogen for steel blanketing, chemical processing, and merchant tube-trailer filling. Hydrexia delivered an integrated, automated PSA-and-TSA purification system that turns 30 million Nm³ of waste gas per year into 8,000 kg/day of 99.999% hydrogen — all feeding the same campus that produced it. The plant has been running since 2017 with no failures in nine years.

The Challenge

A hydrogen-rich waste stream — and a campus already paying for hydrogen.

Wintinwe’s chlor-alkali operation produces a continuous stream of waste gas: roughly 95% hydrogen, 4% water, and 1% nitrogen, CO2, and other contaminants. Untreated, it’s a low-value byproduct. Meanwhile, the same site needed reliable, five-nines hydrogen for three different uses — a steel blanketing atmosphere, chemical processing, and tube-trailer filling for merchant sales through Rishion Gas.

The molecule was already on site. The problem was scrubbing it to pipeline grade — 99.999% H2, 0.0002% O2, −65 °C dew point — every hour, for years, without a babysitter. And the system needed to flex: feedstock supply could change, downstream demand could grow, and the plant had to absorb both without disruption.

Customer Pain Points

Valuable hydrogen, locked in a waste stream

30 million Nm³/year of 95% H₂ gas — too dirty to use, too valuable to vent.

Three downstream users, one purity floor

Steel blanketing, chemical processing, and merchant tube-trailer filling all demand 99.999% purity — no margin for variability.

Minimal staffing, maximum reliability

Continuous chemical operations can’t carry a large crew to nurse the plant — and downstream lines can’t tolerate unplanned downtime.

What Hydrexia Delivered

An integrated, automated purification train — built for flexibility, instrumented for remote control.

Hydrexia designed and delivered a complete PSA-plus-TSA purification system, sized for the waste-gas volume and tuned to the campus’s downstream specs. Raw waste gas (95% H₂, 4% H₂O, 1% N₂/CO₂/other) enters a buffer with integral water knockout, is compressed to 18 bar, and moves through a six-vessel PSA train — one in processing, six in regeneration — to strip out the bulk impurities.

From the PSA, the stream passes through two thermal swing adsorption (TSA) stages — first for residual oxygen removal (deoxo), then for final drying — and into H₂ buffer storage before being delivered to:

  • 85–90% of output → on-campus pipeline to steel blanketing and chemical processing
  • 10–15% of output → merchant tube-trailer filling (Rishion Gas)

PSA tail gas isn’t wasted either: it’s routed to the site boiler to generate steam, improving overall site efficiency.

The whole system runs under 24/7 remote monitoring, with automation built specifically to reduce on-site manpower and leave room for future expansion. When the upstream waste-gas supply was briefly unavailable, the site switched to a lower-purity hydrogen feed — Hydrexia verified compatibility, approved the change, and the plant kept running. That’s real-world flexibility, not just design flexibility.

The outcome

Nine Years. Zero Failures.

Waste gas converted, not vented
0 million Nm³/yr
Pure hydrogen output
kg/day
H2 purity (5 nines)
0 %
Residual O2
0 %

Preventive maintenance on process controls. Deoxo media replaced once. Everything else just runs.

"Carefree Operation."

Chongqing Wintinwe Chlor-Alkali Chemical Company, Ltd.